Direct observation of polymer crystallization process under shear by a shear flow observation system
نویسندگان
چکیده
منابع مشابه
Brownian motion in shear flow: direct observation of anomalous diffusion.
Brownian motion in a simple shear flow has been experimentally investigated by using a different method for observation and analysis. A number of polystyrene spheres dispersed in sheared water were tracked with a confocal scanning laser microscope, and the time dependences of their coordinates were obtained. Since in the usual mean-square displacement in the flow direction the contribution from...
متن کاملThree-dimensional observation of an immiscible polymer blend subjected to a step electric field under shear flow.
We have investigated the structural change of an immiscible blend consisting of two polymers with equal viscosity subjected to a step electric field under shear flow. During the process, three-dimensional images were successfully acquired with a confocal scanning laser microscope, and at the same time, the transient shear stress was also measured. From the images, the interface tensor was calcu...
متن کاملCyclic motion of a grafted polymer under shear flow.
The long-time dynamics of a single end-tethered chain under shear flow are studied using molecular and Brownian dynamics simulations of a flexible polymer. As observed in previous experiments with tethered DNA [Phys. Rev. Lett. 84, 4769 (2000)], under a flow sheared at constant rate the chain performs a cyclic motion. But, contrary to what has been previously suggested, a well-defined character...
متن کاملPersistence of a Rouse polymer chain under transverse shear flow.
We consider a single Rouse polymer chain in two dimensions in the presence of a transverse shear flow along the x direction and calculate the persistence probability P0(t) that the x coordinate of a bead in the bulk of the chain does not return to its initial position up to time t. We show that the persistence decays at late times as a power law P0(t) approximately t{-theta} with a nontrivial e...
متن کاملCrystallization kinetics of colloidal spheres under stationary shear flow.
A systematic experimental study of dispersions of charged colloidal spheres is presented on the effect of steady shear flow on nucleation and crystal growth rates. In addition, the nonequilibrium phase diagram as it relates to the melting line is measured. Shear flow is found to strongly affect induction times, crystal growth rates, and the location of the melting line. The main findings are th...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Polymer Testing
سال: 2003
ISSN: 0142-9418
DOI: 10.1016/s0142-9418(02)00057-0